α-卤代酰胺参与的氮杂环构建方法的研究进展
Research Progress in the Construction of Nitrogen Heterocycle Participated by α-Haloamide
投稿时间:2020-09-14  修订日期:2020-10-23
DOI:
中文关键词: α-卤代酰胺  氮氧烯丙基阳离子  氮杂环化合物  [3 + m]-环加成/环化反应
英文关键词: α-Haloamide  Azaoxyallyl cation  Nitrogen heterocyclic compound  [3 + m]-cycloaddition/cyclization reaction
基金项目:
作者单位E-mail
汪钢强 中南民族大学药学院 wgq20008@163.com 
王航 湖北科技学院非动力核技术研发中心  
孙绍发 湖北科技学院非动力核技术研发中心  
吴滨 中南民族大学药学院  
刘吉开 中南民族大学药学院 jkliu@ mail.kib.ac.cn 
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中文摘要:
      杂环化合物在医药、农药、材料和精细化工品等许多领域发挥着重要作用,因此,开发新颖,有效的合成策略构建杂环化合物一直是人们关注的重点。本文中,我们重点介绍了2011至2020年期间α-卤代酰胺原位产生氮氧烯丙基阳离子通过[3 + m]-环加成/环化反应构建含氮杂环化合物的最新进展。
英文摘要:
      Heterocyclic compounds are widely found in many natural isolates and medicinally relevant compounds, as well as some fine chemicals. The development of general and efficient methods for the construction of heterocyclic compounds is one of the most important tasks in synthetic organic chemistry. In this article, we focus on [3+m]-cycloaddition/cyclization reactions involving in situ generated azaoxyallyl cations as the 3-atom units have emerged as a powerful method for the synthesis of nitrogen-containing heterocycles from 2011 to 2020.
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